INFRARED SPECTRA OF COMPLEXES OF 4-PYRIDONES

Author:

Cook Denys

Abstract

The infrared spectra of many complexes of Lewis acids with some 4-pyridones have been recorded. Large shifts to lower frequencies of about 100 cm−1 have been observed in a band near 1560 cm−1 as the Lewis acid strength increased. Much smaller shifts of about 5 to 10 cm−1 in a band near 1640 cm−1 were noted. The former band has therefore been designated as the carbonyl frequency, and the latter as a ring mode involving CC stretching.The donor site of 4-pyridones is therefore the carbonyl group, and not the nitrogen atom. Protonated 4-pyridones have similar spectra, and are consistent with O-, not N-protonation.

Publisher

Canadian Science Publishing

Subject

Organic Chemistry,General Chemistry,Catalysis

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