Interpretation of the Unusual Fluid Distribution in the Yufutsu Gas-Condensate Field

Abstract

Summary It is generally believed that at steady state, a heavy fluid mixture cannot float, without motion, at the top of a light fluid mixture in a cavity. The expectation is that because of pressure diffusion, segregation occurs with the light fluid at the top and the heavy fluid at the bottom. We present, for the first time, an extensive set of measurements in 5-km vertical wells in a large hydrocarbon formation of 1-km thickness with horizontal dimensions on the order of several kilometers that show a high-density fluid mixture at the top of a light-density fluid mixture at steady state. The data in the 5-km wells show liquid in the middle, and vapor at the top and bottom. In the hydrocarbon formation, there is a gradual decrease of density with depth. A theoretical model based on the thermodynamics of irreversible processes is used to provide an interpretation of the unusual density variation vs. depth both in the hydrocarbon formation and in the long wells, as well as the unusual species distribution in the hydrocarbon formation. The results reveal that thermal diffusion (caused by geothermal temperature gradient) causes the segregation of heavy components in the subsurface fluid mixture to the cold side in the Earth (that is, the top), overriding pressure and molecular diffusion (Fickian diffusion). As a consequence of the competition of these three diffusion effects, a heavy fluid mixture can float at the top with a light fluid mixture underneath. In the past, thermal diffusion has been thought of as a second-order effect. For the fluid mixture in our work, thermal diffusion is the main phenomenon affecting the spatial density and species distribution.