Four-co-ordinate rhodium(I) complexes [{Rh(CO)2Cl}n(α-diimine)] (n = 1, 2) with σ,σ-N,N′ chelate or σ-N, σ-N′ bridge bonded RNC(R′)C(R″)NR ligands. Influence of the branching at Cα of R on the RhIα-diimine interaction-Reference-Cited by-同舟云学术

Four-co-ordinate rhodium(I) complexes [{Rh(CO)2Cl}n(α-diimine)] (n = 1, 2) with σ,σ-N,N′ chelate or σ-N, σ-N′ bridge bonded RNC(R′)C(R″)NR ligands. Influence of the branching at Cα of R on the RhIα-diimine interaction

Published:1981-01 Issue: Volume:51 Page:253-262
ISSN:0020-1693
Container-title:Inorganica Chimica Acta
language:en
Short-container-title:Inorganica Chimica Acta

Author:

Van Der Poel Henk,Van Koten Gerard,Vrieze Kees

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference20 articles.

1. Syntheses and NMR studies of five-co-ordinate rhodium(I) complexes with α-diimines (RNC(H)C(H)NR): [RhCl(CO)(η2-C2H4)(α-diimine)] and [RhCl(L)2(α-diimine)] (R = t−Bu, EtMe2C−; L = CO,PF3)

2. σ,σ′-N,N′ bridging and σ,σ-N,N chelating α diimines. Molecular geometries of [PtCl2PBu3]2(t-BuNCHCHNBu-t) and PtCl2(styrene)(t-BuNCHCHNBu-t)

3. Synthesis and molecular geometry of [trans-PtCl2PBu3]2(di-t-Bu-diimine) containing a σ,σ′-N,N′ bridging diimine with a planar anti-(trans-PPNCCNPtPtrans)- skeleton

4. A Comparative Study of Platinum Di (t-butyl) (15N2)diimine andtrans-[(PtCl2(N-ligand)PBu3)] complexes by195Pt-,31P- and15N-NMR

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