Syntheses and NMR studies of five-co-ordinate rhodium(I) complexes with α-diimines (RNC(H)C(H)NR): [RhCl(CO)(η2-C2H4)(α-diimine)] and [RhCl(L)2(α-diimine)] (R = t−Bu, EtMe2C−; L = CO,PF3)-Reference-Cited by-同舟云学术

Syntheses and NMR studies of five-co-ordinate rhodium(I) complexes with α-diimines (RNC(H)C(H)NR): [RhCl(CO)(η2-C2H4)(α-diimine)] and [RhCl(L)2(α-diimine)] (R = t−Bu, EtMe2C−; L = CO,PF3)

Published:1981-01 Issue: Volume:51 Page:241-252
ISSN:0020-1693
Container-title:Inorganica Chimica Acta
language:en
Short-container-title:Inorganica Chimica Acta

Author:

Van Der Poel Henk,Van Koten Gerard,Vrieze Kees

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference37 articles.

1. Novel bonding modes of .alpha.-diimines. Synthesis and characterization of [MCl2L(.alpha.-diimine)] and [MCl2(.alpha.-diimine)n] (M = palladium, platinum; L = phosphine, arsine; n = 1, 2) containing .sigma.,.sigma.-N,N', .sigma.-N, or .sigma.-N .tautm. .sigma.-N' bonded .alpha.-diimines

2. Synthesis and molecular geometry of [trans-PtCl2PBu3]2(di-t-Bu-diimine) containing a σ,σ′-N,N′ bridging diimine with a planar anti-(trans-PPNCCNPtPtrans)- skeleton

3. .sigma.2-N', .mu.2-N, .eta.2-C:N Coordination as the activating step in the carbon-carbon bond formation between two .alpha.-diimines in dinuclear ruthenium carbonyl complexes. X-ray structure of tetracarbonylbis[glyoxalbis(isopropylimine)]diruthenium

4. The eight electron donor mode of 1,4-diazabutadiene ligands as revealed by the crystal structures of Ru2(CO)4(η-2-acetylene)[σ,σ,η2,η2-glyoxalbis(isopropylimine)] and Ru4(CO)8[σ,σ,η2,η2-glyoxalbis(isopropylimine)]

5. L. H. Staal, L. H. Polm, K. V. Vrieze, F. Ploeger and C. H. Stam, Inorg. Chem., in press.

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