Reactions of bis(iminophosphoranyl)methanes with chloro-bridged rhodium or iridium dimers giving complexes in which the ligand is coordinated either as a σ-N,σ-N′ or as a σ-N, σ-C chelate. X-ray crystal structure of the σ-N, σ-N′ Rh(I) complex Rh{(4-CH3-C6H4-NPPh2)2CH2}(COD)]PF6-Reference-Cited by-同舟云学术

Reactions of bis(iminophosphoranyl)methanes with chloro-bridged rhodium or iridium dimers giving complexes in which the ligand is coordinated either as a σ-N,σ-N′ or as a σ-N, σ-C chelate. X-ray crystal structure of the σ-N, σ-N′ Rh(I) complex Rh{(4-CH3-C6H4-NPPh2)2CH2}(COD)]PF6

Published:1991-06 Issue:1 Volume:184 Page:73-87
ISSN:0020-1693
Container-title:Inorganica Chimica Acta
language:en
Short-container-title:Inorganica Chimica Acta

Author:

Imhoff Pieter,van Asselt Rob,J. Elsevier Cornelis,C. Zoutberg Martin,H. Stam Casper

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference81 articles.

1. α-Diimines as monodentate or bridging ligands; synthesis and characterization of palladium(II) and rhodium(I) di(t-butyl)diimine complexes

2. Synthesis and molecular geometry of [trans-PtCl2PBu3]2(di-t-Bu-diimine) containing a σ,σ′-N,N′ bridging diimine with a planar anti-(trans-PPNCCNPtPtrans)- skeleton

3. Four-co-ordinate rhodium(I) complexes [{Rh(CO)2Cl}n(α-diimine)] (n = 1, 2) with σ,σ-N,N′ chelate or σ-N, σ-N′ bridge bonded RNC(R′)C(R″)NR ligands. Influence of the branching at Cα of R on the RhIα-diimine interaction

4. 1,4-Diaza-1,3-butadiene (α-Diimine) Ligands: Their Coordination Modes and the Reactivity of Their Metal Complexes

Cited by 56 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Phosphonium Ylides vs Iminophosphoranes: The Role of the Coordinating Ylidic Atom in cis-[Phosphine-Ylide Rh(CO)₂] Complexes;Inorganic Chemistry;2023-01-27

2. Heavy Group 15 Element Compounds of a Sterically Demanding Bis(iminophosphorane)methanide and -methanediide;Organometallics;2013-12-09

3. Palladium complexes derived from N,N-bidentate NH-iminophosphorane ligands: synthesis and use as catalysts in the Sonogashira reaction;Dalton Transactions;2012

4. Rhodium carbonyl complexes of bulky, anionic nitrogen-based ligands: A comparison of donating ability;Journal of Organometallic Chemistry;2011-07

5. Coordination Behavior of the S–C–S Monoanion and O–C–O and S–C–S Dianions toward Co II;European Journal of Inorganic Chemistry;2011-04-21