Preparation, properties and reactions with sulfur dioxide in the solid state of complexes of the type [Mn(Ph2E(O)YE(O)Ph2)2(H2O)2](ClO4)2 (E=As, P; Y=C2H4, cis-C2H2). The formation of bis-sulfur dioxide complexes which contain both weakly bound and strongly bound sulfur dioxide-Reference-Cited by-同舟云学术

Preparation, properties and reactions with sulfur dioxide in the solid state of complexes of the type [Mn(Ph2E(O)YE(O)Ph2)2(H2O)2](ClO4)2 (E=As, P; Y=C2H4, cis-C2H2). The formation of bis-sulfur dioxide complexes which contain both weakly bound and strongly bound sulfur dioxide

Published:1992-04 Issue:2 Volume:194 Page:227-231
ISSN:0020-1693
Container-title:Inorganica Chimica Acta
language:en
Short-container-title:Inorganica Chimica Acta

Author:

Banda Samual F.,El-Sayrafi Oraib,McAuliffe Charles A.,Matear Philomena P.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference24 articles.

1. Preparation, properties, and reactions with sulphur dioxide of triphenylphosphine oxide complexes of manganese(II) thiocyanate. Crystal structures of [{Mn(OPPh3)2(NCS)(µ-NCS)}2], [Mn(OPPh3)4(NCS)2], and (PPh3O)(PPh3OH)(HSO4), a derivative of sulphuric acid formed under ambient air oxidation of sulphur dioxide

2. Structure of Triphenylarsane Diiodide,[Ph3As· I2], a Compound Formed in the Thermal Decomposition of[Mn(OAsPh3)3I2(SO2)2]

3. Three forms of (triphenylarsine)diiodine: two polymorphs of C18H15AsI2 and a 1:3/2 toluene solvate C18H15AsI2.3/2C7H8

4. Notes. Reaction of manganese(II) arsine oxide complexes with sulphur dioxide: some unexpected products. The X-ray crystal structure of [(Ph3AsO)2H]I3

5. The X-ray crystal structure of trans-bis(sulphur dioxide)tetrakis(triphenylphosphineoxide)manganese(II) di-iodide, a compound which undergoes demi-reversible binding of sulphur dioxide: the first crystallographically characterised example of O-bonded sulphur dioxide in a transition metal complex

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