Preparation, properties, and reactions with sulphur dioxide of triphenylphosphine oxide complexes of manganese(II) thiocyanate. Crystal structures of [{Mn(OPPh3)2(NCS)(µ-NCS)}2], [Mn(OPPh3)4(NCS)2], and (PPh3O)(PPh3OH)(HSO4), a derivative of sulphuric acid formed under ambient air oxidation of sulphur dioxide
Author:
Publisher
Royal Society of Chemistry (RSC)
Subject
General Chemistry
Link
http://pubs.rsc.org/en/content/articlepdf/1990/DT/DT9900001243
Reference33 articles.
1. The coordination of dioxygen and other small molecules by manganese(II) phosphine complexes
2. The co-ordination of small molecules by manganese(II) phosphine complexes. Part 3. The dependence on the nature of the halogen in [MnX2(PR3)](X = Cl, Br, or I; R3= PhMe2, PhEt2, PhPrn 2, PhBun 2, PhBui 3, Prn 3, Bun 3, or Ph3) on adduct formation with sulphur dioxide in the solid state and in tetrahydrofuran solution
3. Structure of Triphenylarsane Diiodide,[Ph3As· I2], a Compound Formed in the Thermal Decomposition of[Mn(OAsPh3)3I2(SO2)2]
4. Three forms of (triphenylarsine)diiodine: two polymorphs of C18H15AsI2 and a 1:3/2 toluene solvate C18H15AsI2.3/2C7H8
5. Notes. Reaction of manganese(II) arsine oxide complexes with sulphur dioxide: some unexpected products. The X-ray crystal structure of [(Ph3AsO)2H]I3
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