Synthesis of the azatricyclic core of FR901483 by bridgehead vinylation via an anti-Bredt iminium ion
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference10 articles.
1. FR901483, a Novel Immunosuppressant Isolated from Cladobotryum sp. No. 11231. Taxonomy of the Producing Organism, Fermentation, Isolation,Physico-chemical Properties and Biological Activities.
2. Total Synthesis of (−)-FR901483
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4. Yamamoto, H. In Organometallics in Synthesis; Schlosser, M., Ed.; Wiley: Chichester, 1994; Chapter 7, pp. 509–533.
5. For the reported preparation of trivinylaluminum from divinylmercury ((CH2CH)2Hg) and Al metal powder, cf.: Mandal, B. M.; Kennedy, J. P.; Kiesel, R. J. Polym. Sci.1978, 16, 821–831.
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