Relative anion stabilities and transition state energies regarding vinylic vs allylic deprotonation of cyclic vinyl ethers by organolithium reagents: An ab initio study-Reference-Cited by-同舟云学术

Relative anion stabilities and transition state energies regarding vinylic vs allylic deprotonation of cyclic vinyl ethers by organolithium reagents: An ab initio study

Published:1998-07 Issue:29 Volume:54 Page:8371-8392
ISSN:0040-4020
Container-title:Tetrahedron
language:en
Short-container-title:Tetrahedron

Author:

Power Trevor D.,Sebastian John F.

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference38 articles.

1. Direct observation of acyl anion equivalents by carbon-13 Fourier transform nuclear magnetic resonance

2. Allylic vs. vinylic deprotonation reactions of cyclic vinyl ethers. 7-Lithio-2,3,4,5-tetrahydrooxepin: synthesis and carbon-13 NMR spectrum

3. Vinylic vs allylic deprotonation: An ab initio molecular orbital study of 2,3-dihydrooxepin and 1,3-cycloheptadiene

4. Ab initio and semiempirical molecular orbital studies of alpha and beta lithiated vinyl ethers

5. Mechanistic evidence for ortho-directed lithiations from one- and two-dimensional NMR spectroscopy and MNDO calculations

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1. Base or nucleophile? DFT finally elucidates the origin of the selectivity between the competitive reactions triggered by MeLi or LDA on propanal;Chemical Communications;2015

2. ChemInform Abstract: Relative Anion Stabilities and Transition State Energies Regarding Vinylic vs Allylic Deprotonation of Cyclic Vinyl Ethers by Organolithium Reagents: An ab initio Study.;ChemInform;2010-06-19

3. First Stereospecific Synthesis of (E)- or (Z)-α-Fluoroenones via a Kinetically Controlled Negishi Coupling Reaction;The Journal of Organic Chemistry;2006-05-01

4. Density functional study of the lithiation of cyclic vinyl ethers in solution;Tetrahedron;2004-11

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