Migratory-insertion reactions involving the thiocarbonyl ligand. dihapto-thioacyl complexes from the rearrangement of arylthiocarbonyl complexes of osmium(II). Structure of Os(η2-CSR)(η1-O2CCF3)(CO)(PPh3)2-Reference-Cited by-同舟云学术

Migratory-insertion reactions involving the thiocarbonyl ligand. dihapto-thioacyl complexes from the rearrangement of arylthiocarbonyl complexes of osmium(II). Structure of Os(η2-CSR)(η1-O2CCF3)(CO)(PPh3)2

Published:1983-12 Issue:2 Volume:259 Page:215-232
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Clark G.R.,Collins T.J.,Marsden K.,Roper W.R.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference43 articles.

1. Stepwise reduction of the thiocarbonyl ligand: hydride transfer to CS: thioformyl, thioformaldehyde, methylthiolato, secondary carbene, formyl and iminoformyl complexes of osmium

2. Five and six CO-ordinate σ-aryl derivatives of Ru(II) and Os(II) and the equilibrium RuRX(CO)2 (PPh3)2⇄ Ru[C(O)R]X(CO) (PPh3)2

3. Dihapto-acyl derivatives of ruthenium(II). Preparation and structure of Ru[η2-C(O)CH3] I(CO)(PPh3)2 and Ru[η2-C(O)p-tolyl]I(C0) (PPh3) 2

4. A dihapto-iminoacyl derivative of ruthenium(II). Synthesis and structure of RU[η2-C(NR)R]Cl(CO)(PPh3)2

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