Affiliation:
1. Research School of Chemistry, Australian National University, Canberra, Australian Capital Territory, ACT 2601, Australia
Abstract
Independently unstable thiocabonylphosphorane ligands SCPR3 are observed in the complexes [W(η2-SCPR3)(CO)2(Tp*)]+ (PR3 = PCy3, PMenPh3−n: n = 0, 1, 2) arising from the reactions of phosphoniocarbynes [W(CPR3)(CO)2(Tp*)]PF6 with sulfur.
Funder
Australian Research Council
Publisher
Royal Society of Chemistry (RSC)
Subject
Materials Chemistry,Metals and Alloys,Surfaces, Coatings and Films,General Chemistry,Ceramics and Composites,Electronic, Optical and Magnetic Materials,Catalysis
Cited by
2 articles.
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