Halogenoalkyl complexes of the transition metals VII. The synthesis and properties of the ω-halogenoalkyl complexes [(η-C5R5)(CO)2Fe(CH2)nX] (R = H, n = 3–10, X = Br, I; R = CH3, n = 3

Halogenoalkyl complexes of the transition metals VII. The synthesis and properties of the ω-halogenoalkyl complexes [(η-C5R5)(CO)2Fe(CH2)nX] (R = H, n = 3–10, X = Br, I; R = CH3, n = 3–5, X = Br, I)

Published:1990-03 Issue:3 Volume:384 Page:325-338
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Friedrich Holger B.,Makhesha Patrick A.,Moss John R.,Williamson Bridget K.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference19 articles.

1. Activation of dichloromethane by basic rhodium(I) and iridium(I) phosphine complexes. Synthesis and structures of fac-[Rh(PMe3)3Cl2(CH2PMe3)]Cl·CH2Cl2and trans-[Rh(Me2PCH2CH2PMe2)2Cl(CH2Cl)]Cl

2. A route to heteronuclear .mu.-methylene complexes by oxidative addition

3. Synthesis and reactivity of pentamethylcyclopentadienylruthenium formyl and .alpha.-hydroxy complexes

4. Haloalkyl complexes of the transition metals

5. Binuclear platinum complexes with polymethylene bridges: a neighbouring atom effect in oxidative addition

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1. Syntheses, structural elucidation and reactions of allylamino compounds of the type, [η5-C5R5(CO)2Fe(NH2CH2CHCH2)]BF4;Polyhedron;2012-06

2. Synthesis, characterization and structural elucidation of water-soluble 1-aminoalkane and α,ω-diaminoalkane complexes of the pentamethylcyclopentadienyliron dicarbonyl cation, [Cp∗(CO)2Fe]+;Inorganica Chimica Acta;2012-03

3. Synthesis, characterization and reactions of the transition metal halogenoalkyl carbocation complexes [Cp(CO)2M{η2-CH2CH(CH2)nX}]PF6 (n=1–8, 10, M=Fe; n=3, 4 M=Ru; X=Br, I);Journal of Organometallic Chemistry;2008-10

4. Synthesis and characterization of transition metal stabilized carbocations of the types [Cp∗(CO)2Fe{μ-(CnH2n−1}M(CO)xCp]PF6 (x=2, M=Fe or Ru; x=3, M=W, Cp∗=η5-C5(CH3)5; Cp=η5-C5H5; n=3–6) and [Cp(CO)2Ru{μ-(CnH2n−1)}W(CO)3Cp]PF6 (n=3–5) and the crystal structures of the complexes [Cp∗(CO)2Fe(CH2)3Ru(CO)2Cp], [Cp∗(CO)2Fe(CH2)5Ru(CO)2Cp], [Cp∗(CO)2Fe-(CH2)5W(CO)3Cp], and [Cp(CO)2Ru(CH2)5W(CO)3Cp];Journal of Organometallic Chemistry;2007-05

5. Synthesis of Cp‘Ru(CO)(L)(η2-olefin)+ Complexes and Kinetic Studies of Olefin Substitution;Organometallics;2007-03-01