Synthesis and characterization of transition metal stabilized carbocations of the types [Cp∗(CO)2Fe{μ-(CnH2n−1}M(CO)xCp]PF6 (x=2, M=Fe or Ru; x=3, M=W, Cp∗=η5-C5(CH3)5; Cp=η5-C5H5; n=3–6) and [Cp(CO)2Ru{μ-(CnH2n−1)}W(CO)3Cp]PF6 (n=3–5) and the crystal structures of the complexes [Cp∗(CO)2Fe(CH2)3Ru(CO)2Cp], [Cp∗(CO)2Fe(CH2)5Ru(CO)2Cp], [Cp∗(CO)2Fe-(CH2)5W(CO)3Cp], and [Cp(CO)2Ru(CH2)5W(CO)3Cp]-Reference-Cited by-同舟云学术

Synthesis and characterization of transition metal stabilized carbocations of the types [Cp∗(CO)2Fe{μ-(CnH2n−1}M(CO)xCp]PF6 (x=2, M=Fe or Ru; x=3, M=W, Cp∗=η5-C5(CH3)5; Cp=η5-C5H5; n=3–6) and [Cp(CO)2Ru{μ-(CnH2n−1)}W(CO)3Cp]PF6 (n=3–5) and the crystal structures of the complexes [Cp∗(CO)2Fe(CH2)3Ru(CO)2Cp], [Cp∗(CO)2Fe(CH2)5Ru(CO)2Cp], [Cp∗(CO)2Fe-(CH2)5W(CO)3Cp], and [Cp(CO)2Ru(CH2)5W(CO)3Cp]

Published:2007-05 Issue:12 Volume:692 Page:2456-2472
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Changamu Evans O.,Friedrich Holger B.,Rademeyer Melanie

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference49 articles.

1. [μ-1κC1:2(C2,C3-η)-Allyl]tetracarbonyl-1κ2C,2κ2C-(1η5-cyclopentadienyl)(2η5-pentamethylcyclopentadienyl)diiron(II) hexafluorophosphate

2. [μ-1κC1:2(C2,C3-η)-Allyl]tetracarbonyl-1κ2C,2κ2C-(1η5-cyclopentadienyl)(2η5-pentamethylcyclopentadienyl)rutheniumiron hexafluorophosphate

3. Studies on some alkyl and olefin complexes of iron and manganese

4. Hydride Addition to Some π-Bonded Olefin-Iron Complexes

5. 28. Allyl and olefin complexes of iron

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