Equilibrium studies on metalmetal bond dissociation in the [(C5Me5)Cr(CO)3]2 dimer by use of NMR spectroscopy
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Reference25 articles.
1. Metal clusters in catalysis. 20. The chemistry of bis[.eta.5-cyclopentadienyl(tricarbonyl)chromium]
2. Chemistry of [CpCr(CO)3]2. An insertion mechanism for the formation of Cp2Cr2(CO)5Se2 and Cp2Cr2(CO)4Se2 from Cp2Cr2(CO)4Se. Carbonylation and crystal structure of Cp2Cr2(CO)4Se2
3. Chemistry of the organochromium(I) radical CpCr(CO)3.bul.. X-ray structure of a stable derivative, CpCr(CO)2(PPh3).bul.
4. Substitution reactions of the 17-electron complex {η5-C5H5Cr(CO)3}
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1. Direct observation of reversible bond homolysis by 2D EXSY NMR;Chemical Science;2022
2. Reactions of Sn(Si( Bu)2Me)3 with HM(CO)3C5R5 (M = Cr or Mo, R = H or CH3) and Hg. Ionic, covalent, and μ-CO bonding patterns between transition metals and tin;Inorganica Chimica Acta;2018-01
3. Significant O–H Bond Weakening in CpMn(CO)2(CH3OH): Evidence for the Generation of the CpMn(CO)2(CH3O) Radical upon H Atom Abstraction by O2;Organometallics;2013-07-23
4. (Cyclopentadienyl)chromiumtricarbonyl dimers as a source of metal-centered free-radicals to form stable η2-bonded spin-adducts with fullerenes;Journal of Organometallic Chemistry;2005-04
5. Homolytic Cleavage and Aggregation Processes in Cyclopentadienylchromium Chemistry;Accounts of Chemical Research;2004-01-20
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