Synthesis and photochemistry of spiro[2.5]octa-1,4-dien-3-ones. Reversible biradical formation and biradical-olefin cycloaddition
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference9 articles.
1. The Photolysis of Spiro[2.5]octa-1,4-dien-3-one in Ethyl Ether. A Note on the Mechanism of Photolysis of 2,5-Cyclohexadienones
2. The Photolysis of Spiro[2.5]octa-4,7-dien-6-one. Radical Fragmentation in the Photochemistry of 2,5-Cyclohexadienones1
3. Evidence for a 1,2-Hydrogen-Atom Migration in a Photochemically Generated Diradical1,2
4. Stereospecificity and wavelength dependence in the photochemical rearrangement of spiro[2.5]octa-4,7-dien-6-ones to quinone methides
5. An improved procedure for the conversion of3,3-disubstituted-1,4-cyclohexadienes to 2,5-cyclohexadien-1-ones
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1. P(NMe2)3-Mediated Umpolung Spirocyclopropanation Reaction of p-Quinone Methides: Diastereoselective Synthesis of Spirocyclopropane-Cyclohexadienones;Organic Letters;2020-10-12
2. Diastereoselective synthesis of spiro-cyclopropanyl-cyclohexadienones via direct sulfide-catalyzed [2 + 1] annulation of para-quinone methides with bromides;Organic & Biomolecular Chemistry;2020
3. Spirocyclopropanation Reaction of para-Quinone Methides with Sulfonium Salts: The Synthesis of Spirocyclopropanyl para-Dienones;The Journal of Organic Chemistry;2016-03-04
4. ChemInform Abstract: Synthesis and Photochemistry of Spiro(2.5)octa-1,4-dien-3-ones. Reversible Biradical Formation and Biradical-Olefin Cycloaddition.;ChemInform;2010-08-04
5. Synthesis and reactions of hydroxyspiro[5.2]cyclooctenones based on the cyclization of the dianions of acetone and diethyl 2-oxopropylphosphonate with 1,1-diacylcyclopropanes;Tetrahedron Letters;2008-03
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