Diastereoselective synthesis of spiro-cyclopropanyl-cyclohexadienones via direct sulfide-catalyzed [2 + 1] annulation of para-quinone methides with bromides

Author:

Su Yingpeng1234ORCID,Zhao Yanan1234ORCID,Chang Bingbing1234ORCID,Ling Qinqin1234,Feng Yawei1234,Zhao Xiaolong1234,Huang Danfeng1234,Wang Ke-Hu1234,Huo Congde1234ORCID,Hu Yulai1234ORCID

Affiliation:

1. College of Chemistry and Chemical Engineering

2. Northwest Normal University

3. Lanzhou 730070

4. P. R. China

Abstract

A sulfide-catalyzed [2 + 1] annulation of para-quinone methides with diverse bromides was disclosed to access appealing spiro-cyclopropanyl-cyclohexadienones with high diastereoselectivity.

Funder

National Natural Science Foundation of China

Publisher

Royal Society of Chemistry (RSC)

Subject

Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

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