Protecting group controlled diastereoselective reduction of diprotected α,α-bis(hydroxymethyl)ketones derived from THYM*, using the DIBALH / MgBr2 system-Reference-Cited by-同舟云学术

Protecting group controlled diastereoselective reduction of diprotected α,α-bis(hydroxymethyl)ketones derived from THYM*, using the DIBALH / MgBr2 system

Published:1993-01 Issue:34 Volume:34 Page:5483-5486
ISSN:0040-4039
Container-title:Tetrahedron Letters
language:en
Short-container-title:Tetrahedron Letters

Author:

Guanti Giuseppe,Banfi Luca,Riva Renata,Zannetti M.Teresa

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference16 articles.

1. Chemoenzymic preparation of asymmetrized tris(hydroxymethyl)methane (THYM*) and of asymmetrized bis(hydroxymethyl)acetaldehyde (BHYMA*) as new highly versatile chiral building blocks

2. Asymmetrized trils (hydroxymethyl)methane as a highly stereodivergent chiral building block: preparation of all four stereoisomers of protected 2-hydroxymethyl-1,3-butanediol

3. Enantiospecific and diastereoselective synthesis of C11-C17 fragment of tylonolide from “asymmetrized tris (hydroxymethyl)methane”

4. Protecting group controlled diastereoselective allylation of asymmetrized bis (hydroxymethyl)acetaldehydes (BHYMA*)

5. Synthesis of both top and bottom fragments of (-)-talaromycin A through enantiospecific and diastereoselective elaboration of asymmetrized tris (hydroxymethyl)methane

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