New route to the synthesis of polycyclic compounds based on a stepwise AdE-reaction of dicobalt hexacarbonyl complexes of conjugated enynes with a subsequent intramolecular Khand-Pauson type reaction.
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference9 articles.
1. USES OF COBALT-CARBONYL ACETYLENE COMPLEXES IN ORGANIC SYNTHESIS?
2. A simple organocobalt mediated synthesis of substituted 3-oxabicyclo[3.3.0]oct-6-en-7-ones
3. Stereoselectivity of intramolecular dicobalt octacarbonyl alkene-alkyne cyclizations: short synthesis of dl-coriolin
4. Preparation of bicyclo[3.3.0]oct-1-en-3-one and bicyclo[4.3.0]non-1(9)-en-8-one via intramolecular cyclization of .alpha.,.omega.-enynes
5. Synthesis of the angularly fused triquinane skeleton via intramolecular organometallic cyclization
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