Application of Pauson–Khand reaction in the total synthesis of terpenes-Reference-Cited by-同舟云学术

Application of Pauson–Khand reaction in the total synthesis of terpenes

Published:2021 Issue:61 Volume:11 Page:38325-38373
ISSN:2046-2069
Container-title:RSC Advances
language:en
Short-container-title:RSC Adv.

Author:

Heravi Majid M.¹^ORCID,Mohammadi Leila¹

Affiliation:

1. Department of Chemistry, School of Physics and Chemistry, Alzahra University, Vanak, Tehran, Iran

Abstract

The Pauson–Khand reaction (PKR) is a formal [2 + 2 + 1] cycloaddition involving an alkyne, an alkene and carbon monoxide mediated by a hexacarbonyldicobaltalkyne complex to yield cyclopentenones in a single step.

Funder

Alzahra University

Publisher

Royal Society of Chemistry (RSC)

Subject

General Chemical Engineering,General Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2021/RA/D1RA05673E

Reference382 articles.

1. USES OF COBALT-CARBONYL ACETYLENE COMPLEXES IN ORGANIC SYNTHESIS?

2. Organocobalt complexes. Part II. Reaction of acetylenehexacarbonyldicobalt complexes, (R1C2R2)Co2(CO)6, with norbornene and its derivatives

3. The utility of vinyl ethers and vinyl esters in the Khand reaction. The value of vinyl esters as ethylene equivalents and a modified synthesis of (+)-taylorione as an example

4. Peter Ludwig Pauson (1925-2013)

5. Preparation of bicyclo[3.3.0]oct-1-en-3-one and bicyclo[4.3.0]non-1(9)-en-8-one via intramolecular cyclization of .alpha.,.omega.-enynes

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