Failure of the linear correlation of log with AdCl in the solvolysis of tertiary benzylic chlorides. The establishment of a new scale based on 2-aryl-2-chloroadamantanes
Author:
Publisher
Elsevier BV
Subject
Organic Chemistry,Drug Discovery,Biochemistry
Reference11 articles.
1. The Correlation of Solvolysis Rates
2. Solvent assistance in the solvolysis of secondary substrates. I. The 2-adamantyl system, a standard for limiting solvolysis in a secondary substrate
3. The SN2-SN1 spectrum. 4. The SN2 (intermediate) mechanism for solvolyses of tert-butyl chloride: a revised Y scale of solvent ionizing power based on solvolyses of 1-adamantyl chloride
4. Correlation of the rates of solvolysis of 2-adamantyl 2,2,2-trifluoroethanesulfonate: a YOTr scale
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