Highly stereocontrolled reduction of α′-alkoxyenones to give either the threo or eryhtro allylic 1,2-diol. Assignment of the threo configuration to the C-15, C-16 diol of pumiliotoxin B.1-Reference-Cited by-同舟云学术

Highly stereocontrolled reduction of α′-alkoxyenones to give either the threo or eryhtro allylic 1,2-diol. Assignment of the threo configuration to the C-15, C-16 diol of pumiliotoxin B.1

Published:1982-01 Issue:23 Volume:23 Page:2355-2358
ISSN:0040-4039
Container-title:Tetrahedron Letters
language:en
Short-container-title:Tetrahedron Letters

Author:

Overman Larry E.,McCready Russell J.

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference15 articles.

1. A new class of indolizidine alkaloids from the poison frog, Dendrobates tricolor. X-ray analysis of 8-hydroxy-8-methyl-6-(2'-methylhexylidene)-1-azabicyclo[4.3.0]nonane

2. Enantiospecific total synthesis of dendrobatid toxin 251D. A short chiral entry to the cardiac-active pumiliotoxin A alkaloids via stereospecific iminium ion-vinylsilane cyclizations

3. Approach vector analysis: a stereochemical approach to reactivity

4. Stereocontrol in the synthesis of acyclic systems: applications to natural product synthesis

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