Improved procedure for the generation of allyl cations from simple dibromo ketones. Change of mechanism on reaction with triethyl borate amd zinc. Cycloadditions to conjugated dienes.-Reference-Cited by-同舟云学术

Improved procedure for the generation of allyl cations from simple dibromo ketones. Change of mechanism on reaction with triethyl borate amd zinc. Cycloadditions to conjugated dienes.

Published:1975-01 Issue:50 Volume:16 Page:4487-4490
ISSN:0040-4039
Container-title:Tetrahedron Letters
language:en
Short-container-title:Tetrahedron Letters

Author:

Hoffmann H.M.R.,Iqbal M.N.

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference14 articles.

1. One stage synthesis of bicyclo[3.2.2]nona-6,8-dien-3-ones. Silver trifluoroacetate induced reaction of 2-methoxyallyl bromide with arenes

2. Stereospecific generation of 2-oxyallylic cations from two new sources. Steric course of cycloaddition to conjugated dienes

3. Cycloadditions of cyclic allyl cations to furan. Configuration and conformational analysis of the resulting bridged six-membered rings. Isolation and identification of boat and chair atropisomers

4. Carbon-carbon bond formations promoted by transition metal carbonyls. XI. Method for the generation of a synthetic equivalent of unsubstituted oxyallyl via the bromo ketone-iron carbonyl reaction. New route to thujaplicins

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