7,7-Dimethyl-6,8-dioxabicyclo[3.3.0]oct-3-en-2-one as a synthetic equivalent of ketodicyclopentadiene: a new route to (−)-physostigmine, (−)-physovenine, and (−)-aphanorphine-Reference-Cited by-同舟云学术

7,7-Dimethyl-6,8-dioxabicyclo[3.3.0]oct-3-en-2-one as a synthetic equivalent of ketodicyclopentadiene: a new route to (−)-physostigmine, (−)-physovenine, and (−)-aphanorphine

Published:2001-02 Issue:6 Volume:42 Page:1049-1052
ISSN:0040-4039
Container-title:Tetrahedron Letters
language:en
Short-container-title:Tetrahedron Letters

Author:

Tanaka Keigo,Taniguchi Takahiko,Ogasawara Kunio

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference16 articles.

1. Chiral Preparation of Polyoxygenated Cyclopentanoids

2. A pertinent review, see: Ogasawara, K. J. Syn. Org. Chem. Jpn.1996, 54, 15.

3. A New Chiral Route to Optically Pure 3-Oxodicyclopentadiene: A Versatile Chiral Cyclopentadienone Synthon, via Contra-Steric Diels-Alder Reaction

4. Enantiocontrolled route to natural products using chiral equivalents of cyclopentenone and cyclohexenone

5. We have already demonstrated their equivalent use in an enantiocontrolled synthesis of (+)-estrone in which the Diels–Alder reaction was used as the key reaction, see: Tanaka, K.; Nakashima, H.; Taniguchi, T.; Ogasawara, K. Org. Lett. 2000, 2, 1915.

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