Ligand substitution in HC(O)CCo3(CO)9 with 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Diphosphine ligand fluxionality, decarbonylation of the formyl moiety and competitive P–Ph bond cleavage reactivity
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Reference55 articles.
1. Phosphorus-carbon bond cleavage and tetrahedrane cluster activation in the reaction between bis(diphenylphosphino)maleic anhydride (BMA) and PhCCo3(CO)9. Syntheses, kinetic studies, and x-ray diffraction structures of PhCCo3(CO)7(bma) and [cyclic] Co3(CO)6(.mu.2-.eta.2,.eta.1-C(Ph)C:C(PPh2)C(O)OC(O))(.mu.2-PPh2)
2. Reaction of FcCCo3(CO)9 with 2,3-bis(diphenylphosphino)maleic anhydride (bma). X-ray diffraction structure and redox properties of
3. Unpublished results (R=Me and Cl).
4. Diphosphine Isomerization and C−H and P−C Bond Cleavage Reactivity in the Triosmium Cluster Os3(CO)10(bpcd): Kinetic and Isotope Data for Reversible Ortho Metalation and X-ray Structures of the Bridging and Chelating Isomers of Os3(CO)10(bpcd) and the Benzyne-Substituted Cluster HOs3(CO)8(μ3-C6H4)[μ2,η1-PPhCC(PPh2)C(O)CH2C(O)]
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1. BPCD, bpcd;Catalysis from A to Z;2020-04-19
2. Hydrogenase biomimics containing redox-active ligands: Fe2(CO)4(μ-edt)(κ2-bpcd) with electron-acceptor 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd) as a potential [Fe4–S4]H surrogate;Dalton Transactions;2019
3. Chiral diphosphine derivatives of alkylidyne tricobalt carbonyl clusters – A comparative study of different cobalt carbonyl (pre)catalysts for (asymmetric) intermolecular Pauson–Khand reactions;Polyhedron;2016-01
4. Experimental and Computational Studies of the Isomerization Reactions of Bidentate Phosphine Ligands in Triosmium Clusters: Kinetics of the Rearrangements from Bridged to Chelated Isomers and X-ray Structures of the Clusters Os3(CO)10(dppbz), 1,1-Os3(CO)10(dppbzF4), HOs3(CO)9[μ-1,2-PhP(C6H4-η1)C6H4PPh2], and HOs3(CO)9[μ-1,2-PhP(C6H4-η1)C6F4PPh2];Organometallics;2011-02-22
5. Ligand substitution behavior of Ru6(μ6-C)(CO)17 with unsaturated diphosphines: facile capping of a polyhedral face and photochemically promoted P–C bond cleavage in the clusterRu6(μ6-C)(CO)14(μ3-bpcd);Dalton Trans.;2010
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