Synthesis of the chiral tetrahedral clusters RCCo2NiCp(CO)4(bmf) (R=H, Ph) and thermally promoted diphosphine ligand activation: Regiospecific P–C bond scission and X-ray diffraction structure of Co2NiCp(CO)4[μ2,η2,η1-C(H)CC(PPh2)C(O)OCH(OMe)](μ-PPh2)-Reference-Cited by-同舟云学术

Synthesis of the chiral tetrahedral clusters RCCo2NiCp(CO)4(bmf) (R=H, Ph) and thermally promoted diphosphine ligand activation: Regiospecific P–C bond scission and X-ray diffraction structure of Co2NiCp(CO)4[μ2,η2,η1-C(H)CC(PPh2)C(O)OCH(OMe)](μ-PPh2)

Published:2006-01 Issue:1-2 Volume:691 Page:20-26
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Bott Simon G.,Yang Kaiyuan,Richmond Michael G.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference34 articles.

1. Phosphine Ligand Attack at Both the Methylidyne Cap and the CpNi Center in HCCo2NiCp(CO)6 by 2,3-Bis(diphenylphosphino)maleic Anhydride (bma): P−C Bond Cleavage Reactivity, Kinetics, and X-ray Structures of the Zwitterionic Clusters Co2NiCp(CO)4(μ-CO)[μ2,η2,η1-C(H)PPh2CC(PPh2)C(O)OC(O)] and Co2NiCp(CO)4[μ2,η2,σ-C(H)PPh2CCC(O)OC(O)](μ2-PPh2)

2. Ligand substitution in the mixed-metal cluster PhCCo2Ni(CO)6Cp by 2,3-bis(diphenylphosphino)maleic anhydride (bma): An intimate picture involving the stepwise conversion of the trinuclear cluster PhCCo2Ni(CO)4(η2-bma)Cp to the mononuclear compound CpNi[PPh2CPhCC(PPh2)C(O)OC(O)]

3. CO substitution in the mixed-metal clusters PhCCo2Ni(CO)6Cp and PhCCo2Mo(CO)8Cp by (Z)-Ph2PCH=CHPPh2. X-ray diffraction structures and proof of ligand bridging in PhCCo2Ni(CO)4[(Z)-Ph2PCH=CHPPh2]Cp and PhCCo2Mo(CO)6[(Z)-Ph2PCH=CHPPh2]Cp

4. Darstellung und Eigenschaften von Derivaten des 2,3‐Bis(di‐phenylphosphino)maleinsäure‐anhydrids als Beitrag zum Problem der Farbigkeit, Konjugationsbeeinflussung und Komplexbildung dieser Stoffklasse

5. Diastereoselectivity and Regioselectivity in the Intramolecular Phosphine Attack on a Coordinated Alkyne Ligand in Co2(CO)4(bmf)(.mu.-PhC.tplbond.CH). Formation of the Chiral Hydrocarbyl Complex Co2(CO)4[.mu.-.eta.2,.eta.2,.eta.1,.eta.1-PhC:C(H)PPh2C:C(PPh2)C(O)OCH(OMe)]

Cited by 6 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Isomerization of the diphosphine ligand 3,4-bis(diphenylphosphino)-5-methoxy-2(5H)-furanone (bmf) at a triosmium cluster and P–C bond cleavage in the unsaturated cluster 1,1-Os3(CO)9(bmf): Synthesis and X-ray diffraction structures of the isomeric Os3(CO)10(bmf) clusters and HOs3(CO)8(μ-C6H4)[μ-PhPCC(Ph2P)CH(OMe)OC(O)];Polyhedron;2010-09

2. Ligand substitution behavior of Ru6(μ6-C)(CO)17 with unsaturated diphosphines: facile capping of a polyhedral face and photochemically promoted P–C bond cleavage in the clusterRu6(μ6-C)(CO)14(μ3-bpcd);Dalton Trans.;2010

3. CO Substitution and Cluster-Ligand Reductive Coupling in the Reaction of 2,3-Bis(diphenylphosphino)maleic Anhydride (bma) with the Mixed-metal Clusters PhCCo2MCp(CO)8 (where M = Cr, W): Synthesis and X-ray Diffraction Structures of the Phosphido-bridged Clusters Co2MCp(CO)5[μ2,η2,η1-C(Ph)C=C(PPh2)C(O)OC(O)](μ-PPh2);Journal of Chemical Crystallography;2007-10-30

4. Photochemically promoted regiospecific P–C bond cleavage in the diruthenium compound Ru2(CO)2(bmf): X-ray diffraction structure of Ru2(CO)6[μ-C=C(PPh2)C(O)OCH(OMe)](μ-PPh2);Journal of Coordination Chemistry;2007-07-01

5. Ligand-induced polyhedral opening in the mixed-metal cluster MeCCo2NiCp(CO)6 by 4,5-Bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): X-ray structure of Co2NiCp(CO)4[μ2,η2,η1-C(Me)C=C(PPh2)C(O)CH2C(O)](μ2-PPh2);Journal of Chemical Crystallography;2006-11-07