Isomerization of the diphosphine ligand 3,4-bis(diphenylphosphino)-5-methoxy-2(5H)-furanone (bmf) at a triosmium cluster and P–C bond cleavage in the unsaturated cluster 1,1-Os3(CO)9(bmf): Synthesis and X-ray diffraction structures of the isomeric Os3(CO)10(bmf) clusters and HOs3(CO)8(μ-C6H4)[μ-PhPCC(Ph2P)CH(OMe)OC(O)]-Reference-Cited by-同舟云学术

Isomerization of the diphosphine ligand 3,4-bis(diphenylphosphino)-5-methoxy-2(5H)-furanone (bmf) at a triosmium cluster and P–C bond cleavage in the unsaturated cluster 1,1-Os3(CO)9(bmf): Synthesis and X-ray diffraction structures of the isomeric Os3(CO)10(bmf) clusters and HOs3(CO)8(μ-C6H4)[μ-PhPCC(Ph2P)CH(OMe)OC(O)]

Published:2010-09 Issue:14 Volume:29 Page:2814-2821
ISSN:0277-5387
Container-title:Polyhedron
language:en
Short-container-title:Polyhedron

Author:

Kandala Srikanth,Yang Li,Campana Charles F.,Nesterov Vladimir,Wang Xiaoping,Richmond Michael G.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference52 articles.

1. Bridging versus chelating diphosphine in clusters: Isomers of Os3(CO)10(diphosphine)

2. Protonation and hydrogenation of triosmium clusters containing the bridging diphosphine ligands Ph2P(CH2nPPh2 (n  1 to 4)

3. Synthesis, single-crystal X-ray structures, and fluxional behaviour of 1,2-[Os3(CO)10(µ-dppe)] and its protonated derivative 1,2-[Os3(µ-H)(CO)10(µ-dppe)][PF6] where dppe = Ph2PCH2CH2PPh2

4. Methylene chain length and coordination geometry in triosmium clusters containing diphosphine ligands X-ray crystal structures of [Os3(CO)10{μ-Ph2P(CH2)n}](n = 4 or 5) and [Os3(CO) 8{μ-Ph2PCH2PPh2}2]

5. Chelate and Bridge Diphosphine Isomerization: Triosmium and Triruthenium Clusters Containing 1,1‘-Bis(diphenylphosphino)ferrocene (dppf)

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1. Backbone modified small bite-angle diphosphines: Synthesis, structure, and DFT evaluation of the thermal activation products based on Os3(CO)10{μ-Ph2PC(Me)2PPh2};Journal of Organometallic Chemistry;2014-01

2. 2-[(Diphenylphosphino)methyl]-6-methylpyridine (PN) coordination chemistry at triosmium clusters: Regiospecific ligand activation and DFT evaluation of the isomeric Os3(CO)10(PN) clusters;Journal of Organometallic Chemistry;2013-11

3. Ligand substitution in 1,2-Os3(CO)10(MeCN)2 by the diphosphine (PhO)2PN(Me)N(Me)P(OPh)2: X-ray diffraction structure of 1,2-Os3(CO)10[(PhO)2PN(Me)N(Me)P(OPh)2] and DFT investigation of the isomeric Os3(CO)10[(PhO)2PN(Me)N(Me)P(OPh)2] clusters;Journal of Molecular Structure;2012-02

4. Bonding Structure, Dehydrogenation, and Dimerization of 1,3-C6H4 from Decomposition of 1,3-C6H4I2 on Cu(100);The Journal of Physical Chemistry C;2011-11-04

5. New osmium cluster compounds containing the heterocyclic ligand 2,3-bis-(diphenylphosphino)quinoxaline (dppq): Ligand isomerization and crystal structures of dppq, the isomeric clusters Os3(CO)10(dppq), and HOs3(CO)9[μ-2,3-PhP(η1-C6H4)(Ph2P)quinoxaline];Journal of Organometallic Chemistry;2011-04