Ligand substitution in the tetrahedrane clusters RCCo2Mo(η5-indenyl)(CO)8 with 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Influence of the carbyne and indenyl ligands on the stability of the substitution products and X-ray diffraction structures of HCCo2Mo(η5-indenyl)(CO)6(μ-bpcd) and CoMo(η5-indenyl)(μ-CPh)(CO)2(μ-bpcd)Cl-Reference-Cited by-同舟云学术

Ligand substitution in the tetrahedrane clusters RCCo2Mo(η5-indenyl)(CO)8 with 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Influence of the carbyne and indenyl ligands on the stability of the substitution products and X-ray diffraction structures of HCCo2Mo(η5-indenyl)(CO)6(μ-bpcd) and CoMo(η5-indenyl)(μ-CPh)(CO)2(μ-bpcd)Cl

Published:2006-12 Issue:26 Volume:691 Page:5567-5575
ISSN:0022-328X
Container-title:Journal of Organometallic Chemistry
language:en
Short-container-title:Journal of Organometallic Chemistry

Author:

Watson William H.,Poola Bhaskar,Richmond Michael G.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference53 articles.

1. Phosphorus-carbon bond cleavage and tetrahedrane cluster activation in the reaction between bis(diphenylphosphino)maleic anhydride (BMA) and PhCCo3(CO)9. Syntheses, kinetic studies, and x-ray diffraction structures of PhCCo3(CO)7(bma) and [cyclic] Co3(CO)6(.mu.2-.eta.2,.eta.1-C(Ph)C:C(PPh2)C(O)OC(O))(.mu.2-PPh2)

2. Reaction of FcCCo3(CO)9 with 2,3-bis(diphenylphosphino)maleic anhydride (bma). X-ray diffraction structure and redox properties of

3. Ligand substitution in HC(O)CCo3(CO)9 with 4,5-bis(diphenylphosphino)-4-cyclopenten-1,3-dione (bpcd): Diphosphine ligand fluxionality, decarbonylation of the formyl moiety and competitive P–Ph bond cleavage reactivity

4. CO replacement in the tetrahedrane cluster MeC(O)CCo3(CO)9 by the diphosphine ligand 4,5-bis(diphenylphosphino)-4-cyclopenten-l,3-dione (bpcd): Diphosphine ligand isomerization and X-ray structure of the bridged cluster MeC(O)CCo3(CO)7(bpcd)

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