Mechanism of interconversion of the silica-supported tin alkyl complexes (SiO)3-nSn(n-C4H9)n+1, n = 0, 1, 2. Synthesis and characterization of the tin-containing polyhedral oligo-silsesquioxanes [(c-C5H9)7Si8O12(CH3)2Sn(n-C4H9)3], [(c-C5H9)7Si7O11 (OH)Sn(n-C4H9)2] and [(c-C5H9)7Si7O12Sn(n-C4H9)] as possible models for the expected surface structures
Author:
Publisher
Elsevier BV
Subject
General Chemical Engineering,General Chemistry
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1. Silica-surface reorganization during organotin grafting evidenced by 119Sn DNP SENS: a tandem reaction of gem-silanols and strained siloxane bridges;Phys. Chem. Chem. Phys.;2014
2. On silsesquioxanes’ accuracy as molecular models for silica-grafted complexes in heterogeneous catalysis;Coordination Chemistry Reviews;2010-03
3. Silica-Supported Zirconium Complexes and their Polyoligosilsesquioxane Analogues in the Transesterification of Acrylates: Part 1. Synthesis and Characterization;Advanced Synthesis & Catalysis;2009-09
4. Grafting Reaction of Organotin Complexes on Silica Catalyzed by Tungstic Heteropolyacids;Inorganic Chemistry;2009-08-25
5. Understanding the reactivity of [WNAr(CH2tBu)2(CHtBu)] (Ar=2,6-iPrC6H3) with silica partially dehydroxylated at low temperatures through a combined use of molecular and surface organometallic chemistry;Journal of Organometallic Chemistry;2006-12
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