Changes in excited-state character of [M(L 1 )(L 2 )(CO) 2 (α-diimine)] (M=Ru, Os) induced by variation of L 1 and L 2
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Physical and Theoretical Chemistry,Inorganic Chemistry
Reference36 articles.
1. The Remarkable Photochemistry of fac-XMn(CO)3(.alpha.-diimine) (X =Halide): Formation of Mn2(CO)6(.alpha.-diimine)2 via the mer Isomer and Photocatalytic Substitution of X- in the Presence of PR3
2. Real-time Fourier transform IR (FTIR) spectroscopy in organometallic chemistry: mechanistic aspects of the fac to mer photoisomerization of fac-[Mn(Br)(CO)3(R-DAB)]
3. Character and picosecond dynamics of the excited states of [Re(Br)(CO)3(α-diimine)] complexes as a function of the α-diimine ligand: 4,4′-di-methyl-2,2′-bipyridine, N,N-di-p-tolyl-1,4-diaza-butadiene and N,N-di-p-anisyl-1,4-diaza-butadiene
4. Halide-Dependent Change of the Lowest-Excited-State Character from MLCT to XLCT for the Complexes Re(X)(CO)3(α-diimine) (X = Cl, Br, I; α-diimine = bpy, iPr-PyCa, iPr-DAB) Studied by Resonance Raman, Time-Resolved Absorption, and Emission Spectroscopy
5. Alkyl-dependent photochemistry of Mn (R)(CO)3(R′-DAB) (R = Me, Bz; R′ = iPr, pTol): homolysis of the MnR bond for R = Bz and release of CO for R = Me
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