Halide-Dependent Change of the Lowest-Excited-State Character from MLCT to XLCT for the Complexes Re(X)(CO)3(α-diimine) (X = Cl, Br, I; α-diimine = bpy, iPr-PyCa, iPr-DAB) Studied by Resonance Raman, Time-Resolved Absorption, and Emission Spectroscopy-Reference-Cited by-同舟云学术

Halide-Dependent Change of the Lowest-Excited-State Character from MLCT to XLCT for the Complexes Re(X)(CO)3(α-diimine) (X = Cl, Br, I; α-diimine = bpy, iPr-PyCa, iPr-DAB) Studied by Resonance Raman, Time-Resolved Absorption, and Emission Spectroscopy

Published:1996-01-01 Issue:10 Volume:35 Page:2902-2909
ISSN:0020-1669
Container-title:Inorganic Chemistry
language:en
Short-container-title:Inorg. Chem.

Author:

Rossenaar Brenda D.¹,Stufkens Derk J.¹,Vlček Antonín¹

Affiliation:

1. Anorganisch Chemisch Laboratorium, J. H. van't Hoff Research Institute, Universiteit van Amsterdam, Nieuwe Achtergracht 166, 1018 WV Amsterdam, The Netherlands, and J. Heyrovský Institute of Physical Chemistry, Academy of Sciences of the Czech Republic, Dolejškova 3, 182 23 Prague, Czech Republic

Publisher

American Chemical Society (ACS)

Subject

Inorganic Chemistry,Physical and Theoretical Chemistry

Link

https://pubs.acs.org/doi/pdf/10.1021/ic9509802

Reference57 articles.

1. Characterization of metal-to-ligand charge-transfer and intraligand transitions of fac-[Re(CO)3L(X)] complexes [L = di-imine; X = halide or Mn(CO)5] and explanation of the photochemistry of [Re(CO)3L{Mn(CO)5}] using the resonance Raman effect

2. Application of the energy gap law to nonradiative, excited-state decay

3. Structural, spectral, and charge-transfer properties of ClRe(CO)3(2-PP) [2-PP = N-(2-pyridinylmethylene)phenylamine] and ClRe(CO)3(2-PC) [2-PC = N-(2-pyridinylmethylene)cyclohexylamine]

4. Excited-state properties and reactivity of [ReCL(CO)3(2,2′-bipy)](2,2′-bipy = 2,2′-bipyridyl) studied by time-resolved infrared spectroscopy

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