Cluster self-assembly of centered cubes of copper(I) with dialkyldithiophosphate ligands. X-ray structures of [Cu8(DDP)6(μ8-X)]PF6 (DDP=S2P(OiPr)2; X=Cl or Br) and their relationship to oxide and sulfide centered zinc(II) dialkyldithiophosphates, [Zn4(DDP)6(μ4-S or O)]-Reference-Cited by-同舟云学术

Cluster self-assembly of centered cubes of copper(I) with dialkyldithiophosphate ligands. X-ray structures of [Cu8(DDP)6(μ8-X)]PF6 (DDP=S2P(OiPr)2; X=Cl or Br) and their relationship to oxide and sulfide centered zinc(II) dialkyldithiophosphates, [Zn4(DDP)6(μ4-S or O)]

Published:2004-11 Issue:13 Volume:357 Page:3950-3956
ISSN:0020-1693
Container-title:Inorganica Chimica Acta
language:en
Short-container-title:Inorganica Chimica Acta

Author:

Liu C.W.,Irwin Michael D.,Mohamed Ahmed A.,Fackler John P.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference50 articles.

1. Copper(I) 1,1-dithiolate cluster transformations. Synthesis of [Bu4N]6[Cu6(S,i-MNT)6], i-MNT=[S2CC(CN)2]−, from [Bu4N]4[Cu8(i-MNT)6] with sulfur. Reaction of the cyclic hexanuclear complex with phosphine to give the tetrahedral [Bu4N]4[Cu4(i-MNT)4] which oxidizes in solution to give the homocubane [Bu4N]4[Cu8(i-MNT)6] and [Bu4N]2[Cu(i-MNT)2]

2. Use of preassembled iron/sulfur and iron/molybdenum/sulfur clusters in the stepwise synthesis of potential analogs for the Fe/Mo/S site in nitrogenase

3. Synthesis and Reactivities of Cubane-Type Sulfido Clusters Containing Noble Metals

4. Chalcogenide-bridged cuboidal clusters with M4Q4 (M = Mo, W; Q = S, Se, Te) cores

5. Structure, bonding and electron counts in cubane-type cluster having M4S4, M2M′2S4 and MM′3S4 cores

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