Copper(I) 1,1-dithiolate cluster transformations. Synthesis of [Bu4N]6[Cu6(S,i-MNT)6], i-MNT=[S2CC(CN)2]−, from [Bu4N]4[Cu8(i-MNT)6] with sulfur. Reaction of the cyclic hexanuclear complex with phosphine to give the tetrahedral [Bu4N]4[Cu4(i-MNT)4] which oxidizes in solution to give the homocubane [Bu4N]4[Cu8(i-MNT)6] and [Bu4N]2[Cu(i-MNT)2]-Reference-Cited by-同舟云学术

Copper(I) 1,1-dithiolate cluster transformations. Synthesis of [Bu4N]6[Cu6(S,i-MNT)6], i-MNT=[S2CC(CN)2]−, from [Bu4N]4[Cu8(i-MNT)6] with sulfur. Reaction of the cyclic hexanuclear complex with phosphine to give the tetrahedral [Bu4N]4[Cu4(i-MNT)4] which oxidizes in solution to give the homocubane [Bu4N]4[Cu8(i-MNT)6] and [Bu4N]2[Cu(i-MNT)2]

Published:1998-07 Issue:1 Volume:174 Page:147-177
ISSN:0010-8545
Container-title:Coordination Chemistry Reviews
language:en
Short-container-title:Coordination Chemistry Reviews

Author:

Liu C.W.,Staples Richard J.,Fackler John P.

Publisher

Elsevier BV

Subject

Materials Chemistry,Physical and Theoretical Chemistry,Inorganic Chemistry

Reference100 articles.

1. J.M. Walshe, in: J. Peisach, P. Aisen, W.E. Plumberg, (Eds.), The Biochemistry of Copper, Academic Press, New York, 1966, p. 475.

2. M.C. Linder, Biochemistry of Copper, Plenum Press, New York, 1991.

3. W. Hoffmann, Rubber Technology Handbook, Hanser, Münich, 1989.

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