The oxidative addition of SnCl4 to [W(CO)4(NCMe)(PPh3)]. The X-ray crystal structure of [WH(CO)3(NCMe)(PPh3)2][SnCl5·MeOH]
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry
Reference41 articles.
1. The Organometallic Chemistry of Halocarbonyl Complexes of Molybdenum(II) and Tungsten(II)
2. Seven-coordinate halocarbonyl complexes of the type [MXY(CO)3(NCMe)2] (M = Mo, W; X, Y = halide, pseudo halide) as highly versatile starting materials
3. Use of the seven-coordinate complexes [MXY(CO)3(NCMe)2] (M=Mo or W; X, Y=halide) and their derivatives in homogeneous catalysis
4. Spectroscopic properties, structure and reactivity of [WCl(SnCl3)(CO)3(NCMe)2]
5. Synthesis, structure and reactivity of novel W–Ge chlorocarbonyl compounds. X-ray crystal structure of [WCl(GeCl3)(CO)3(NCEt)2]
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1. Lewis Bases Trigger Intramolecular CH–Bond Activation: ( t Bu 3 SiO) 2 W=N t Bu [rlhar2] ( t Bu 3 SiO)(κ O ,κ C ‐ t Bu 2 SiOCMe 2 CH 2 )HW=N t Bu;European Journal of Inorganic Chemistry;2013-05-10
2. An Update on WIIand MoIICarbonyl Precursors and Their Application in the Synthesis of Potentially Bio-Inspired Thiophenolate-Oxazoline Complexes;Zeitschrift für anorganische und allgemeine Chemie;2013-04-30
3. Reactivity Studies of (tBu3SiNH)(tBu3SiN═)2WH Including Anionic Derivatives Featuring the Tris-tri-tert-butylsilylimide Tungsten Core;Organometallics;2011-11-30
4. A novel dianionic seven-coordinate complex of tungsten(II), [WCl3(GeCl3)(CO)3]2−: Synthesis, spectroscopic properties and X-ray crystal structure;Inorganic Chemistry Communications;2007-10
5. Activation of the Si–H bond of Et2SiH2 in photochemical reaction with W(CO)6: Spectroscopic characterization of intermediate W–Si compounds and the revisited crystal structure of the bis{(μ-η2-hydridodiethylsilyl)tetracarbonyltungsten(I)} complex [{W(μ-η2-H–SiEt2)(CO)4}2];Journal of Organometallic Chemistry;2007-08
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