Highly enantioselective synthesis of β-hydroxy nitriles by the cyanomethylation of aldehydes using DPMPM as a chiral catalysts or ligand
Author:
Publisher
Elsevier BV
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Catalysis
Reference20 articles.
1. Enantioface-differentiating Reactions Using (2S,2′S)-2-Hydroxymethyl-1-[(1-alkyl-2-pyrrolidinyl)methyl]pyrrolidines as Chiral Ligands. Addition of Lithium Derivatives of Methyl Phenyl Sulfide, Acetonitrile,N-Nitrosodimethylamine, and 2-Methylthiothiazoline to Aldehydes
2. Enhanced enantioselectivity of an enzymatic reaction by the sulfur functional group. A simple preparation of optically active .beta.-hydroxy nitriles using a lipase
3. Preparation of Optically Pure α-Alkyl β-Hydroxy Nitriles by the Bakers’ Yeast Reduction
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2. Biocatalytic asymmetric ring-opening of dihydroisoxazoles: a cyanide-free route to complementary enantiomers of β-hydroxy nitriles from olefins;Green Chemistry;2020
3. Enantioselective addition of diethylzinc to aldehydes catalyzed by 5-cis-substituted proline derivatives;Tetrahedron;2019-01
4. Electrophile-Dependent Alkylations of Lithiated 4-Alkoxyalk-4-enenitriles;The Journal of Organic Chemistry;2018-02-16
5. Preparation of enantiomerically enriched aromatic β-hydroxynitriles and halohydrins by ketone reduction with recombinant ketoreductase KRED1-Pglu;Tetrahedron;2016-07
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