Oxidative route to polyoxomolybdates from quadruply bonded [MoIIMoII] precursor: Structural characterization of a tetranuclear cluster [Mo4Cl5O8(pyNP)2] (pyNP=(2-(2-pyridyl)1,8-naphthyridine))
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry
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5. Synthesis and structural investigation of polyoxomolybdate coordination compounds displaying a tetranuclear core. Crystal and molecular structures of [Bu4N]2[Mo4O10(OMe)2(OC6H4O)2] and to the diazenido complexes [Bu4N]2[Mo4O6(OMe)2(HNC6H4O)2(NNC6H5)4] and [Bu4N]2[Mo4O6(OMe)2(C10H6O2)2(NNC6H5)4]. Comparison to a binuclear complex with the [Mo2(OMe)2(NNC6H5)4]2+ core, [Mo2(OMe)2(H2NC6H4O)]
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1. PYNP, pynp, pyNP;Catalysis from A to Z;2020-04-18
2. Monomeric and Dimeric Oxidomolybdenum(V and VI) Complexes, Cytotoxicity, and DNA Interaction Studies: Molybdenum Assisted C═N Bond Cleavage of Salophen Ligands;Inorganic Chemistry;2017-08-31
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4. Electronic tuning of Mo2(thioamidate)4 complexes through π-system substituents and cis/trans isomerism;Dalton Trans.;2014
5. Mixed-ligand compounds incorporating quadruply bonded dimolybdenum(II) core: Syntheses, structures and reactivity studies;Inorganica Chimica Acta;2010-10
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