Oxidomolybdenum complexes for acid catalysis using alcohols as solvents and reactants-Reference-Cited by-同舟云学术

Oxidomolybdenum complexes for acid catalysis using alcohols as solvents and reactants

Published:2016 Issue:13 Volume:6 Page:5207-5218
ISSN:2044-4753
Container-title:Catalysis Science & Technology
language:en
Short-container-title:Catal. Sci. Technol.

Author:

Gomes Ana C.¹²³⁴⁵,Neves Patrícia¹²³⁴⁵,Cunha-Silva Luís⁶¹⁷⁸⁹,Valente Anabela A.¹²³⁴⁵,Gonçalves Isabel S.¹²³⁴⁵,Pillinger Martyn¹²³⁴⁵

Affiliation:

1. Department of Chemistry

2. CICECO - Aveiro Institute of Materials

3. University of Aveiro

4. 3810-193 Aveiro

5. Portugal

6. REQUIMTE/LAQV

7. Faculty of Sciences

8. University of Porto

9. 4169-007 Porto

Abstract

With ethanol as solvent and reactant, a molybdenum (pre)catalyst promotes selective acid-catalysed reactions. Depending on the conditions, the Mo^VIcomplex is converted to Mo^VIoxidoalkoxido, Mo^Voxido-bridged dinuclear, and Mo^VIoctanuclear complexes.

Funder

Fundação para a Ciência e a Tecnologia

Publisher

Royal Society of Chemistry (RSC)

Subject

Catalysis

Link

http://pubs.rsc.org/en/content/articlepdf/2016/CY/C5CY02052B

Reference91 articles.

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2. Applications of Dioxomolybdenum(VI) Complexes to Organic Synthesis

3. High-valent oxo-molybdenum and oxo-rhenium complexes as efficient catalysts for X–H (X = Si, B, P and H) bond activation and for organic reductions