Relative bond dissociation energies for early transition metal alkyl, aryl, alkynyl and hydride compounds. Equilibration of metallated cyclopentadienyl derivatives of peralkylated hafnocene and scandocene with hydrocarbons and dihydrogen-Reference-Cited by-同舟云学术

Relative bond dissociation energies for early transition metal alkyl, aryl, alkynyl and hydride compounds. Equilibration of metallated cyclopentadienyl derivatives of peralkylated hafnocene and scandocene with hydrocarbons and dihydrogen

Published:1988-01 Issue:16-17 Volume:7 Page:1409-1428
ISSN:0277-5387
Container-title:Polyhedron
language:en
Short-container-title:Polyhedron

Author:

Bulls A.Ray,Bercaw John E.,Manriquez Juan M.,Thompson Mark E.

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry

Reference23 articles.

1. .beta.-Hydride elimination from methoxo vs. ethyl ligands: thermolysis of (DPPE)Pt(OCH3)2, (DPPE)Pt(CH2CH3)(OCH3) and (DPPE)Pt(CH2CH3)2

2. .sigma.-Bond metathesis for carbon-hydrogen bonds of hydrocarbons and Sc-R (R = H, alkyl, aryl) bonds of permethylscandocene derivatives. Evidence for noninvolvement of the .pi. system in electrophilic activation of aromatic and vinylic C-H bonds

3. Reductive elimination of isobutane from an isobutyl hydride derivative of bis(pentamethylcyclopentadienyl)zirconium

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