Photolysis of Tp′Rh(CNneopentyl)(PhNCNneopentyl) in the presence of ketones and esters: kinetic and thermodynamic selectivity for activation of different aliphatic C

Photolysis of Tp′Rh(CNneopentyl)(PhNCNneopentyl) in the presence of ketones and esters: kinetic and thermodynamic selectivity for activation of different aliphatic C–H bonds

Published:2019 Issue:29 Volume:48 Page:10945-10952
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Parsons Astrid M.¹²³⁴^ORCID,Jones William D.¹²³⁴^ORCID

Affiliation:

1. Department of Chemistry

2. University of Rochester

3. Rochester

4. USA

Abstract

The competitive activation of the various C–H bonds found in ketones and esters by a trispyrazolylborate rhodium complex are compared.

Funder

Basic Energy Sciences

Division of Chemistry

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2019/DT/C9DT01802F

Reference34 articles.

1. C–H bond activation enables the rapid construction and late-stage diversification of functional molecules

2. Recent applications of C–H functionalization in complex natural product synthesis

3. Activation of carbon-hydrogen bonds in saturated hydrocarbons on photolysis of (.eta.5-C5Me5)(PMe3)IrH2. Relative rates of reaction of the intermediate with different types of carbon-hydrogen bonds and functionalization of the metal-bound alkyl groups

4. A structural, kinetic and thermodynamic study of the reversible thermal carbon-hydrogen bond activation/reductive elimination of alkanes at iridium

5. Reversible carbon-hydrogen bond insertion/reductive elimination in (.eta.5-pentamethylcyclopentadienyl)(trimethylphosphine)iridium complexes. Use in determining relative metal-carbon bond energies and thermally activating methane

Cited by 2 articles. 订阅此论文施引文献订阅此论文施引文献，注册后可以免费订阅5篇论文的施引文献，订阅后可以查看论文全部施引文献

1. Selectivity in the activation of C H bonds by rhodium and iridium complexes;Advances in Organometallic Chemistry;2022

2. Tris(pyrazolyl)borate rhodium complexes. Application for reductive amination and esterification of aldehydes in the presence of carbon monoxide;Journal of Organometallic Chemistry;2020-10