A general synthesis for ditungsten tetracarboxylates. Preparation of WW quadruple bonds by reductive-elimination (alkyl group disproportionation) from 1,2-diethyl compounds with WW triple bonds
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Physical and Theoretical Chemistry
Reference6 articles.
1. Nyholm Lecture. Synergic interplay of experiment and theory in studying metal–metal bonds of various orders
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4. Preparation and characterization of 1,2-dialkyl compounds of dimolybdenum and ditungsten of formula M2R2(NMe2)4 (M.tplbond.M)
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1. trans-Heteroleptic carboxylate-bridged paddlewheel diruthenium(ii, ii) complexes with 2,6-bis(trifluoromethyl)benzoate ligands;Dalton Transactions;2016
2. Electronic and Magnetic Properties of Infinite 1D Chains of Paddlewheel Carboxylates M2(COOR)4 (M = Mo, W, Ru, Rh, Ir, Cu);The Journal of Physical Chemistry C;2013-03-05
3. Ditungsten Tetracarboxylates;Inorganic Syntheses;2007-01-05
4. Alcoholysis of gauche-1,2-(η3-Cp)2W2(NMe2)4: Structural evidence for WW bond cleavage and proton transfer to bound cyclopentadiene;Inorganic Chemistry Communications;2006-10
5. Tungsten to tungsten quadruple bonds: over 30 years of research, 50 structurally characterized compounds and 100 known compounds;Inorganica Chimica Acta;2003-07
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