trans-Heteroleptic carboxylate-bridged paddlewheel diruthenium(ii, ii) complexes with 2,6-bis(trifluoromethyl)benzoate ligands

Author:

Sekine Yoshihiro12345,Kosaka Wataru12345,Kano Hirohisa56789,Dou Changxiao5102114,Yokoyama Taiga5102114,Miyasaka Hitoshi12345

Affiliation:

1. Institute for Materials Research

2. Tohoku University

3. Sendai 980-8577

4. Japan

5. Department of Chemistry

6. Division of Material Sciences

7. Graduate School of Natural Science and Technology

8. Kanazawa University

9. Kanazawa 920-1192

10. Graduate School of Science

11. Sendai 980-8578

Abstract

A series of trans-heteroleptic carboxylate-bridged paddlewheel diruthenium(ii, ii) complexes were synthesized via the ligand-substitution reaction and valence reduction of homoleptic series [Ru2(RCO2)4(THF)2]+ using 2,6-trifluoromethylbenzoate.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

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