Identity of the metal oxide support controls outer sphere interactions that change rates and barriers for alkene epoxidations at isolated Ti atoms

Author:

Zeynep Ayla E.,Patel Darshan,Harris ArzamORCID,Flaherty David W.ORCID

Funder

Army Research Office

Publisher

Elsevier BV

Subject

Physical and Theoretical Chemistry,Catalysis

Reference54 articles.

1. Mechanisms in Homogeneous and Heterogeneous Epoxidation Catalysis;Oyama,2008

2. Propylene epoxidation over titanium-on-silica catalyst—the heart of the SMPO process;Buijink;Catal. Today,2004

3. Do metal peroxides as homolytic and heterolytic oxidative reagents. Mechanism of the halcon epoxidation process;Mimoun;Catal. Today,1987

4. M. Taramasso, G. P., B. Notari Preparation of porous crystalline synthetic material comprised of silicon and titanium oxides. US 4410501, 1983.

5. The Production of Propene Oxide: Catalytic Processes and Recent Developments;Nijhuis;Ind. Eng. Chem. Res.,2006

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