Ti-catalyzed transannular cyclization of epoxygermacrolides. Synthesis of antifungal (+)-tuberiferine and (+)-dehydrobrachylaenolide-Reference-Cited by-同舟云学术

Ti-catalyzed transannular cyclization of epoxygermacrolides. Synthesis of antifungal (+)-tuberiferine and (+)-dehydrobrachylaenolide

Published:2008-12 Issue:52 Volume:64 Page:11938-11943
ISSN:0040-4020
Container-title:Tetrahedron
language:en
Short-container-title:Tetrahedron

Author:

Justicia José,de Cienfuegos Luis Álvarez,Estévez Rosa E.,Paradas Miguel,Lasanta Ana M.,Oller Juan L.,Rosales Antonio,Cuerva Juan M.,Oltra J. Enrique

Publisher

Elsevier BV

Subject

Organic Chemistry,Drug Discovery,Biochemistry

Reference56 articles.

1. Transition-metal-centered radicals in organic synthesis. Titanium(III)-induced cyclization of epoxy olefins

2. Intermolecular addition of epoxides to activated olefins: a new reaction

3. Free radical-mediated reduction and deoxygenation of epoxides

4. Selective Generation of Free Radicals from Epoxides Using a Transition-Metal Radical. A Powerful New Tool for Organic Synthesis

5. Bis(cyclopentadienyl)titanium(III) chloride can be generated in situ by stirring commercial Cp2TiCl2 with Zn or Mn dust in THF, where it exists as an equilibrium mixture of the monomer Cp2TiCl and the dinuclear species [Cp2TiCl]2, see:

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