Demystifying Cp2Ti(H)Cl and Its Enigmatic Role in the Reactions of Epoxides with Cp2TiCl
Author:
Affiliation:
1. Department of Chemistry and Biochemistry, The Ohio State University, 100 West 18th Avenue, Columbus, Ohio 43210, United States
2. Kekulé-Institut für Organische Chemie und Biochemie, Universität Bonn, Gerhard-Domagk-Straße 1, 53121 Bonn, Germany
Funder
Division of Chemistry
Deutsche Forschungsgemeinschaft
Ohio State University
J?rgen Manchot Stiftung
National Institute of General Medical Sciences
Publisher
American Chemical Society (ACS)
Subject
Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry
Link
https://pubs.acs.org/doi/pdf/10.1021/acs.organomet.8b00793
Reference61 articles.
1. Theoretical study on the reaction mechanisms of ethylene with Cp 2 Ti + R, Cp 2 Ti(Cl)R, and Cp 2 Ti(Cl:AlH 2 Cl)R (R=H and CH 3 )
2. Asymmetric Diels-Alder reaction catalyzed by a chiral titanium reagent
3. Ti(III)-catalyzed radical cyclization of 6,7-epoxygeranyl acetate
4. Titanocene-Catalyzed Cascade Cyclization of Epoxypolyprenes: Straightforward Synthesis of Terpenoids by Free-Radical Chemistry
5. 7-endo Radical Cyclizations Catalyzed by Titanocene(III). Straightforward Synthesis of Terpenoids with Seven-Membered Carbocycles
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