Synthesis and structure of [(η5-C5Me5)WCl2(μ-H)]2. A dinuclear tungsten hydride with a double bond formed from the reaction of BH3THF with (η5-C5Me5)WCl4
Author:
Publisher
Elsevier BV
Subject
Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry
Reference21 articles.
1. Synthesis of Cobaltaborane Clusters from [Cp*CoCl]2 and Monoboranes. New Structures and Mechanistic Implications
2. High Yield Synthesis and Characterization of Chromaboranes. Comparison of the Geometric, Electronic, and Chemical Properties of an Electronically Unsaturated (.eta.5-C5Me5)2Cr2B4H8 Cluster with Its Saturated Derivative (.eta.5-C5Me5)2Cr2(CO)2B4H6
3. Synthesis of Novel Molybdaboranes from (η5-C5R5)MoCln Precursors (R = H, Me; n = 1, 2, 4)
4. Synthesis of Mono- and Ditungstaboranes from Reaction of Cp*WCl4 and [Cp*WCl2]2 with BH3·thf or LiBH4 (Cp* = η5-C5Me5). Control of Reaction Pathway by Choice of Monoboron Reagent and Oxidation State of Metal Center
5. Chemistry of Dimetallaboranes Derived from the Reaction of [Cp*MCl2]2 with Monoboranes (M = Ru, Rh; Cp* = η5-C5Me5)
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1. Syntheses and structures of chalcogen-bridged binuclear group 5 and 6 metal complexes;Journal of Chemical Sciences;2019-12
2. Synthesis, Structures, and Characterization of Dimeric Neutral Dithiolato‐Bridged Tungsten Complexes;European Journal of Inorganic Chemistry;2017-12-06
3. Metallaboranes from Metal Carbonyl Compounds and Their Utilization as Catalysts for Alkyne Cyclotrimerization;ChemPlusChem;2014-02-06
4. Lewis Bases Trigger Intramolecular CH–Bond Activation: ( t Bu 3 SiO) 2 W=N t Bu [rlhar2] ( t Bu 3 SiO)(κ O ,κ C ‐ t Bu 2 SiOCMe 2 CH 2 )HW=N t Bu;European Journal of Inorganic Chemistry;2013-05-10
5. Reactivity Studies of (tBu3SiNH)(tBu3SiN═)2WH Including Anionic Derivatives Featuring the Tris-tri-tert-butylsilylimide Tungsten Core;Organometallics;2011-11-30
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