Stabilisierung niedervalenter Ni(CO)-Bausteine durch [Ti](CCR)2; Reaktionsverhalten von {[Ti](CCR)2}Ni(CO) gegenüber Triphenylphosphan und Phosphiten

Author:

Lang H,Meichel E,Stein Th,Weber C,Kralik J,Rheinwald G,Pritzkow H

Publisher

Elsevier BV

Subject

Materials Chemistry,Inorganic Chemistry,Organic Chemistry,Physical and Theoretical Chemistry,Biochemistry

Reference25 articles.

1. A Novel Route to Mixed Transition-Metal Complexes

2. Übersichtsartikel: (a) H. Lang, D.S.A. George, G. Rheinwald, Coord. Chem. Rev. 206–207 (2000) 101;(b) H. Lang, G. Rheinwald, J. Prakt. Chem. 341 (1999) 1;(c) H. Lang, M. Weinmann, Synlett 1 (1996) 1;(d) H. Lang, K. Köhler, S. Blau, Coord. Chem. Rev. 143 (1995) 113;(e) T. Stein, H. Lang, Abhath Al Yarmouk J. 10 (2001) 155;(f) H. Lang, T. Stein, J. Organomet. Chem., Special issue ‘Interactions of π-Systems with Metals’ 641 (2002) 41;(g) H. Lang, M. Leschke, Heteroatom. Chem. 13 (2002) 521;(h) P.J. Low, M.I. Bruce, Adv. Organomet. Chem. 48 (2002) 71;(i) S. Lotz, P.H. van Rooyen, R. Meyer, Adv. Organomet. Chem. 37 (1995) 219;(k) J. Manna, K.D. John, M.D. Hopkins, Adv. Organomet. Chem. 38 (1995) 79;(l) R. Choukroun, P. Cassoux, Acc. Chem. Res. 32 (1999) 494;(m) U. Rosenthal, P.M. Pellny, F.G. Kirchbauer, V.V. Burlakov, Acc. Chem. Res. 33 (2000) 119;Theorie: (n) G. Aullon, S. Alvarez, Organometallics 21 (2002) 2627;(o) E.D. Jemmis, A.K. Phukan, K.T. Giju, Organometallics 21 (2002) 2254;(p) A. Kovacs, G. Frenking, Organometallics 18 (1999) 887.

3. Bis(alkinyl)titanocen–Ni(CO) Komplexe: (a) H. Lang, W. Imhof, Chem. Ber. 125 (1992) 1307;(b) H. Lang, M. Herres, L. Zsolnai, Bull. Chem. Soc. Jpn. 66 (1993) 1;(c) H. Lang, M. Herres, W. Imhof, J. Organomet. Chem. 465 (1994) 283;(d) H. Lang, I.-Y. Wu, S. Weinmann, C. Weber, N. Nuber, J. Organomet. Chem. 541 (1997) 157;(e) S. Back, H. Pritzkow, H. Lang, Organometallics 17 (1998) 41;(f) S. Back, G. Rheinwald, L. Zsolnai, G. Huttner, H. Lang, J. Organomet. Chem. 563 (1998) 73;(g) W. Frosch, S. Back, H. Müller, K. Köhler, A. Driess, B. Schiemenz, G. Huttner, H. Lang, J. Organomet. Chem. 619 (2001) 99.

4. Formation of the first heterobimetallic phosphido-bridged σ–π-acetylide complex [(C5H5)2Ti(µ–σ,η2-CCPh)(µ-PPh2)Ni(PPh3)] by cleavage of the central C–C single bond in PhCC–CCSiMe3and of the P–C bond in Ph3P, and coupling of the fragments to PhCCSiMe3

5. Heterobimetallic .sigma.,.pi.-Acetylide-Bridged Complexes from Disubstituted 1,3-Butadiynes

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