Flow Analysis Techniques for Spatial and Temporal Measurement of Nutrients in Aquatic Systems

Abstract

Environmental Context.Eutrophication is a growing problem globally, and it has significant ecological and socio-economic consequences. Understanding the causes of eutrophication requires a knowledge of nutrient biogeochemistry in aquatic systems. Owing to the high spatial and temporal variability of nutrients in these systems, there is a need for autonomous in situ measurement techniques with rapid response and the ability to collect long-term data. Flow injection analysis is one technique that meets these demands. Abstract.Flow analysis offers a versatile and powerful approach to monitoring of the aquatic environment. The present review highlights the drivers for determining macro- and micro-nutrients in marine and fresh waters, and outlines the instrumental requirements for in situ instrumentation. The principles of flow analysis, specifically flow injection and derivative techniques, and the chemical bases for macro- and micro-nutrient detection are discussed, and key examples of suitable approaches are considered. The successful deployment of flow analysis nutrient monitoring systems for spatial and temporal measurements is illustrated by specific examples relating to surface transects, depth profiles and temporal deployments. Finally, the challenges and imperatives of research in this area are outlined.