Abstract
A variety of bis (ethane-1,2-diamine)cobalt(III) complexes containing chelated β-functionalized amino acids have been treated with SOCl2 in dimethylformamide. These compounds undergo β-elimination reactions to give chelated enamines followed by either rearrangement to the related imine complexes or further reactions with SOCl2 to give chelated isothiazole-3-carboxylato complexes. Mechanisms are proposed for the reactions.
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9 articles.
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