Stereoretentive formylation of (S)-proline: new application of the self-regeneration of stereo-centres (SRS) principle via chelation to cobalt(iii)-Reference-Cited by-同舟云学术

Stereoretentive formylation of (S)-proline: new application of the self-regeneration of stereo-centres (SRS) principle via chelation to cobalt(iii)

Published:2015 Issue:42 Volume:44 Page:18438-18446
ISSN:1477-9226
Container-title:Dalton Transactions
language:en
Short-container-title:Dalton Trans.

Author:

Temizsoy Mehmet¹²³⁴,Sethi Waqas¹²³⁴,Reinholdt Anders¹²³⁴,Schau-Magnussen Magnus¹²³⁴,Bendix Jesper¹²³⁴,Hammershøi Anders¹²³⁴

Affiliation:

1. Department of Chemistry

2. University of Copenhagen

3. DK-2100 Copenhagen Ø

4. Denmark

Abstract

Vilsmeier–Haack-type formylation of ligated (S)-prolinate was achieved stereoselectively at the substitution-inert cobalt(iii) centre. While coordinated, the stereogenic N centre of the (S)-prolinate ligand maintains chirality during reaction.

Publisher

Royal Society of Chemistry (RSC)

Subject

Inorganic Chemistry

Link

http://pubs.rsc.org/en/content/articlepdf/2015/DT/C5DT02674A

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