Affiliation:
1. Department of Mechanical Engineering, University of Florida, Gainesville, FL 32611-6300
Abstract
This paper details the design, implementation, and field evaluation of an online detector system using laser-induced breakdown spectroscopy (LIBS) for the analysis of copper chromated arsenate (CCA) treated wood products. The LIBS-based instrument functioned by creating the laser-induced plasma directly on the sample surface while wood was translated under the detector system, and was successful in discriminating between CCA treated wood and untreated wood products based on the atomic emission signal of chromium. The system was optimized for plasma emission collection both in and out of the laser focal plane and temporally optimized for chromium analysis using a compact, non-intensified charge-coupled device (CCD)/spectrometer unit. Using either single laser pulse spectra or 5-shot and 10-shot spectral averages, the accuracy of LIBS-based analysis ranged from 92 to 100% for identifying both CCA treated and untreated wood samples from the waste stream at a construction and demolition debris recycling center. Additional implementation issues are discussed in the context of LIBS-based on-line sorting of construction and demolition wood debris.
Subject
Spectroscopy,Instrumentation
Cited by
49 articles.
订阅此论文施引文献
订阅此论文施引文献,注册后可以免费订阅5篇论文的施引文献,订阅后可以查看论文全部施引文献