The Raman Scattering of Actinide (VI) Ions in Carbonate Media-Reference-Cited by-同舟云学术

The Raman Scattering of Actinide (VI) Ions in Carbonate Media

Published:1978-11 Issue:6 Volume:32 Page:535-537
ISSN:0003-7028
Container-title:Applied Spectroscopy
language:en
Short-container-title:Appl Spectrosc

Author:

Basile L. J.¹,Ferraro J. R.¹,Mitchell M. L.¹,Sullivan J. C.¹

Affiliation:

1. Chemistry Division, Argonne National Laboratory, Argonne, Illinois 60439

Abstract

Raman scattering of actinide (VI) ions from carbonate media were obtained. Results indicate bidentate complexation of carbonate and linear geometry for the AnO22+ ions. The trend of the frequency position of the ν1 vibration in AnO22+ ions is U > Np > Pu > Am in both acid and basic solutions, with higher frequencies occurring in acid media.

Publisher

SAGE Publications

Subject

Spectroscopy,Instrumentation

Link

http://journals.sagepub.com/doi/pdf/10.1366/000370278774330793

Reference3 articles.

1. The Raman Scattering of Uranyl and Transuranium V, VI, and VII Ions

2. Infrared Spectra of Metal Chelate Compounds. VIII. Infrared Spectra of Co(III) Carbonato Complexes

3. Nakamoto K., Infrared Spectra of Inorganic and Coordination Compounds (Wiley-Interscience, New York, 1970), 2nd Ed., p. 111.

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